Novel non-magnetic hard boride Co5B16 synthesized under high pressure
نویسندگان
چکیده
منابع مشابه
Magnetic properties of the filled skutterudite-type structure compounds GdRu4P12 and TbRu4P12 synthesized under high pressure
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Boron under Pressure: Phase Diagram and Novel High-pressure Phase
Boron has a unique chemistry, responsible for remarkable complexities even in the pure element. I review some of the history of the discovery of this element, and recent surprises found in boron under pressure. I discuss the recent discovery of a new high-pressure phase, γ-B28, consisting of icosahedral B12 clusters and B2 pairs in a NaCl-type arrangement: (B2)(B12), and displaying a significan...
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A new oxoborate β -CaB4O7 has been synthesized under high-pressure/high-temperature conditions from calcium oxide and boron oxide with a Walker-type multianvil apparatus at 7.7 GPa and 1100 ◦C. Single crystal X-ray structure determination of β -CaB4O7 revealed: Pmn21, a = 1058.4(1), b = 436.9(1), c = 419.4(1) pm, Z = 2, R1 = 0.0305, wR2 = 0.0587 (all data). The compound is isotypic to the known...
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ژورنال
عنوان ژورنال: Journal of Alloys and Compounds
سال: 2014
ISSN: 0925-8388
DOI: 10.1016/j.jallcom.2014.04.104